| First,
let's go through the basics to be sure that we're all on the
same page.
HFC132a, 1,1,1,2 tetrafluoroethane, is also known commonly
as "duster gas." Readily available here in the
States. Somewhat harder to get in Europe and other overseas
countries. Brand-names include Tokyo Marui's "Blue
Gas" and Western Arm's "WA GunPower."
Taiwanese
"Green Gas," CH2FCF3CH3. Sold only as proprietary
airsoft propellant gasses. Brand-names include Toy Jack/Top
Gas, HFC, UHC, and Omega. Typically, they are also referred
to as "Super Power Green Gas."
HFC22, more
correctly referred to as HCFC22 (thanks, Phoenix!),
chlorodifuloromethane. Getting true HCFC22 is becoming
harder and harder to obtain in the States as this is on the
"slow-ban" list due to the fact that it is harmful
to the ozone.
Now, to add to
the confusion, the following contribution from Rotor –
Thanks!
R12 is also
known as CFC12, dichlorodifluoromethane. Being a
hydrochlorocarbon with high ozone depleting properties, it
is currently banned from manufacture in the US and many
industrialized countries world-wide. Currently, it is
"reclaimed" and re-used. Production in the US
stopped as of Jan 1, 1996.
HCFC22, which
is chlorodifluoromethane, is, as I’ve mentioned above, on
the "slow-ban" list (it's not "as
harmful"), scheduled for complete cessation of
production by the year 2020.
I’ve yet to
see R12 Freon used in airsoft. Perhaps it was before my
time….. However, I also have yet to see bottled HCFC22 for
airsoft – I simply have not seen this marketed ANYWHERE,
aside from true industrial or refrigeration use. The supply
that I have is from an old cache of scientific laboratory
use coolant which I’ve “jury-rigged” for use…..
Anyone? There is a website that sells bulk canisters of
HCFC22, but without a proper pressure-regulating adaptor,
you’ll run the risk of over pressurizing your fill and (1)
destroying your GBB and (2) possible personal harm to
yourself!
"Red"
and "Black" gasses. Unknown chemical constituency
(I've yet to get a canister of this stuff, or see it in
person). Rumored to only be suitable for use in highly
upgraded GBB's.
The current
consensus among the players as well as recommendations from
certain airsoft GBB manufacturers that Japanese GBB's, ie.
Western Arms, KSC, Maruzen, etc., only be fed HFC134a. As
such, many Stateside players have, instead of paying higher
prices for the TM and WA airsoft specific HFC134a gasses,
gone to jury-rigging fill adaptors in order to use common
"duster gas." This is a perfectly acceptable
alternative, as the chemical constituency for the gasses are
the same. Some players have complained and others warned
that common "duster gas" does not contain any
lubricant, as with the airsoft-specific propellant gasses.
However, this is easily remedied by dropping one or two
drops of silicone oil directly onto the incoming gas fill
nipple and subsequently introducing fill gas into the
magazine. This process causes sufficient atomization of the
lubricant oil into the magazine gas resevoir, which is then
spread throughout the GBB during discharge. There's nothing
wrong with simply spraying or dropping in a bit of silicone
oil at the incoming gas fill port at the bottom of your
magazine immediately prior to each fill as I've suggested.
If anything, when done properly, it will most likely
actually introduce much more than the small percentage of
lubricant actually present in the proprietary airsoft
gasses.
Note that
players in who have used difluoroethane, which is also a
common compound used as "duster gas," have
experienced slightly different performance characteristics
than that of true HFC134a (1,1,1,2 tetrafluoroethane). Most
Japanese-made GBB's are optimized for use with HFC134a --
providing both an outstanding amount of gas-efficiency
(around 80 cycles per fill) coupled with good muzzle
velocity (usually around 250 fps. with 0.20 gram BB's for
the high-end models).
Generally
speaking, the various Taiwanese "Green Gasses"
that I've come across are all of the chemical formula
CH2FCF3CH3. Additionally, all seem to provide the airsoft
GBB with considerably more power (in terms of both
quantitative observed muzzle velocity as well as subjective
feel of "blowback kick/recoil") than HFC134a. Such
an external manifestation of power is most likely reflected
in the internal operating pressure that the GBB is subject
to while using "Green Gasses." Likely as a result
of the mechanical shock of increased "recoil"
energy, in combination with the likely much higher operating
pressures, the stressed parts are thus made more prone to
failure. For whatever reason, Japanese GBB's simply do not
seem to tolerate such abuse as well as their Taiwanese-made
counterparts.
Strangely, many
Taiwanese-made GBB's require the use of the "more
powerful" Taiwanese "Green Gas" in order to
achieve the same muzzle velocity as Japanese GBB's do while
using the considerably "less powerful" HFC134a.
This is perhaps the single factor that demonstrates the
superior performance engineering of the Japanese GBB's.
Ironically, most Japanese GBB's are not built for the abuse
that constant use of Taiwanese "Green Gas" can
inflict on a GBB. The above consensus of using only HFC134a
in Japanese-made GBB's spawned from MANY players' misfortune
of having suffered various broken parts due to the use of
various brands of Taiwanese "Green Gasses" (and
other gasses that are "higher-powered" than
HFC134a) in their expensive Japanese GBB's.
One common
misconception is that "Toy Jack/Top Gas" is
"more powerful" than the various Taiwanese
"Green Gasses." This is not true -- some canisters
of "Top Jack/Toy Jack" gasses come into the US
with an importer affixed label declaring the true chemical
components of its contents. From such labeling, you can
easily see that "Toy Jack/Top Gas" is clearly
CH2FCF3CH3.
Typically,
Taiwanese-made airsoft specific "Green Gasses"
incorporate, as a small percentage of their content, a
silicone additive for lubrication of the gun's vital cyclic
and frictional parts and surfaces -- as well as various
neoprene/rubber o-rings, seals, and gas route packing. This
is easily evidenced by the small amount of oil left over on
the gas route packing membrane after repeated discharge of
the gun.
True HFC22 is
chlorodifluoromethane, a chemical compound that is distinct
from that used in various Taiwanese "Green
Gasses." Yet, many mis-informed individuals insist that
the two are one and the same. This can be easily dis-proved
by a simple chrony and a gas efficiency test. Depending on
the particular GBB's valving and mechanicals, you will more
than likely find a considerable difference in performance in
terms of muzzle velocity and gas efficiency when you
substitute HFC22 for Taiwanese "Green Gas," and
vice-versa; even with identical fill-times and testing
conditions. This only stands to reason if the two gasses are
indeed NOT the same.
While it is not
recommended that you use the various Taiwanese "Green
Gasses" or HFC22 in your Japanese-made GBB, many
players do choose to run that risk in trade for increased
muzzle velocity. Some players have had the bad luck of
having their GBB's literally falling apart in their hands or
"exploding" upon their first use of such
"high-powered" gasses (cited from both the old,
now defunct airsoftguns.com d-board as well as the
airsoftzone.com Forums). Others, however, have not had that
problem, but are undoubtedly exposing their GBB's to a
relatively increased rate of wear compared with their
HFC134a-usage counterparts. Thus, the decision between this
trade-off of performance vs. durability is completely up to
you.
A word of
caution is that players take statements from the Internet
such as "the Tokyo Marui (Japanese) Beretta M9 GBB
pistol can take Taiwanese 'Green Gas' with no problems"
and see that as a license to run the
"higher-powered" gasses in their own M9. The same
can be said of recommendations passed for the Western Arms
High-Capacity series (ie. CQB/TAC/SpeedComp) and Strayer
Voigt Infinity series GBB pistols. While it is true that
they *can* "take" such "higher powered"
gasses, it does not mean that they are immune to the
deleterious effects of such.
The same,
actually, can be said of any and all GBB's, regardless of
manufacture. The use of "higher powered" gasses,
such as Taiwanese "Green Gas," HFC22,
"Red," or even "Black" gas may be
"possible" in your GBB -- but you can bet your ass
that your GBB will likely get fucked up sooner than your
friends' that's been fed an exclusive diet of
"low-powered" HFC134a.
Notes:
(1a) Some stock
Taiwanese GBB's may require the use of the "higher
powered" gasses to function properly.
(1b)
Furthermore, upgraded GBB's, particularly those with metal
slides, may also need to use those gasses for optimal
cycling -- just keep in mind that even though a metal slide
will likely mean that you won't suffer from a cracked/broken
slide due to the increased operating pressure/intensity,
there are always other parts that are also subject to the
abuse.
(2) KWC's
"PowerBombe" gas is something of a puzzle to me.
While the canister clearly declares that it is
"HFC134a," I suspect it to be of the same chemical
constituency as the other Taiwanese "Green
Gasses." Why? [a] My KWC M92FS "Super," when
new, refused to cycle properly with use of true HFC134a --
only with "higher-powered" Taiwanese "Green
Gasses" and true HFC22 did it cycle correctly (this has
since become a non-issue, perhaps due to the mainspring
losing some of its tension over time?). [b] The KWC gas has
the distinctive odor of the Taiwanese "Green
Gasses" -- while not a very scientific observation, it
does leads one to wonder..... [c] Quite a few friends have
pointed out that their GBB's seem to pack an extra punch
when using this particular gas -- which has led them to also
believe, independently, that the KWC claim of this gas being
true HFC134a may be false.
Again I'm
unsure *why* the canister is labeled "HFC134a."
However, this is clearly a "factory/manufacturer"
label, instead of a true "for-import" purpose
"truth-in-labeling" label as affixed to canisters
of airsoft-specific gasses that have been imported into the
country and obtained through, say, a Stateside retailer.
(3) Outgoing
gas "valve." The nozzle on the top of the magazine
-- termed by WA engineers as the "gas route
packing." Like all neoprene/rubber seals, this should
get a little bit of lubrication. The atomized lubricant from
the intake nipple fill process should be sufficient.
However, a little extra on top wouldn't hurt anything. The
only thing that I feel I should caution you about is getting
lubricant oil/grease into the BB feed tube or the feed lip,
which can, at times, cause mis-feeds. As these two parts are
closely situated to each other, use care.
(4) Over-oiling
will cause you to attract dirt and lint particles. Try to
lubricate liberally, yet not overly so. I am sorry that I
cannot describe this better to you, but then again, each of
us probably has a different definition of
"sufficient" lube.
(5)
Difluoroethane. Depending on the precise GBB you have (its
internal valving differences), you will experience either
higher or lower observed muzzle velocity with difluoroethane
as compared to 1,1,1,2 tetrafluoroethane. There may also be
a slight difference in observed gas efficiency, again based
on the exact GBB you have.
An oxidative
by-product of difluoroethane, as I found out from another
player and confirmed with a bit of digging, is formaldehyde.
While formaldehyde is a Class I suspect carcinogen, it is
probably formed in such small quantities that the use of it
in our GBB's really would not constitute a serious concern.
However, I would still recommend against specifically going
to "sniff" the gas. Even so, formaldehyde gas, *I
believe* (someone please correct me if I'm wrong, here)
spontaneously decomposes to formic acid -- which may be
somewhat harmful, in the long run, to the neoprene/rubber
o-rings and seals. Again, though, it is probably formed in
such small amounts as to make this a non-issue. It's more
likely that your various seals will simply expire due to
repeated use.
(6) As a side
note, I should point out that HFC22 is more acidic than
HFC134a -- and that this should also be a concern for those
of you who would like for your GBB's to last a *long* time.
(7) From a
fellow player, Mr. White: “Here is my question - what
happens if i load the clip 1/3 Power Bombe and 2/3 Green
Gas? Or lets say 2/3 HFC134a and 1/2 HCFC22? I have not seen
anything about mixing gases here (i'm not talking about
mixing PC Duster with anything, because obviously that will
do no harm). I mean what reaction takes place (i'm not
looking for a reply like 'you get a bit of a power incease)?”
As for the
intermix of gasses, as you know, that's been proposed by
many players as an "intermediate" between the more
powerful "Green Gas" and HFC134a. However, as to
the true chemical/atomic/molecular intermix, again, it's a
crap shoot. No-one really knows what happens -- empirical
data gathered by other players seem to suggest that some
sort of intermix occurs, but I have not tried this approach
personally, so I can't tell you for sure....
I don't think
that the gasses will "mix" as in create a new
compound -- they're likely inert as they are. As such, the
increase in observed power is likely either due to the
higher pressured gas either being "shared" in the
reservoir equally, or, perhaps, being "sucked up"
in unequal "gulps" -- thereby increasing power on
certain shots randomly, while not on others....
I wish there
could be a better explanation, but my guess is that unless
someone were to somehow tag and then visualize the
individual molecules, no one will know for sure. Meanwhile,
I'm sure that those who have been using the "partial
fill" technique to compensate for power/cost will
continue to do so based on their field-tested
observations/trials!
More of my
thoughts on this subject click here.
(8) Typically,
you can find spray silicone lubricant at the local hardware
store. However, most include some kind of additives as
propellant and also as an evaporative aid. As my own
knowledge of chemistry does not extend that deeply, I tend
to keep things simple, and choose to use 100% silicone
oils/gels from hobby shops.
You can
typically obtain 100% silicone oils in the form of
"Team Associated Shock Oil" from many hobby shops
(or on-line from www.towerhobbies.com,
just use their search function to locate the product).
Anything from 10 to 30 weight will do. |